Brown Pine Tar Safety Data Sheet

The safety data sheet is in accordance with Commission Regulation (EU) 2015/830 of 28 May 2015 amending Regulation
(EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation
and Restriction of Chemicals (REACH)
SECTION 1: Identification of the substance / mixture and of the company /
undertaking
1.1. Product identifier
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
Manufacturer
1.4. Emergency telephone number
SAFETY DATA SHEET
Brown Pine Tar
21.09.2016
Brown Pine Tar
Pine Tar
60530
Wood protection
SU21 Consumer uses: Private households (= general public = consumers)SU22
Professional uses: publicly accessible (administration, education, entertainment,
services, craftsmen)PC9 Coatings and Paints, Fillers, Putties, Thinners
Auson AB
Verkstadsgatan 3
S-434 42
KUNGSBACKA
SVERIGE
+46 300-562000
+46 300-562021
nina.nyth@auson.se
https://www.auson.se/
Nina Nyth
Telephone number: 112
Description: SOS Alarm
Date issued
Product name
Chemical name
Article no.
Use of the substance /
preparation
Relevant identified uses
Company name
Postal address
Postcode
City
Country
Telephone number
Fax
Email
Website
Contact person
Emergency telephone
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SECTION 2: Hazards identification
2.1. Classification of substance or mixture
2.2. Label elements
Hazard pictograms (CLP)
2.3. Other hazards
SECTION 3: Composition / information on ingredients
3.2. Mixtures
Substance Identification Classification Contents
Pine Tar CAS No.: 8011-48-1
EC No.: 232-374-8
Xi; R43
R52/53
Skin Sens. 1;H317
Aquatic Chronic 3; H412
60 – 65 %
Xi; R43
R52/53
Skin Sens. 1; H317
Aquatic Chronic 3; H412
Risk for spontaneous combustion if linseed oil is absorbed by porous organic material
(cotton waste or rag). This oxidation, which give rise to heat can happen even at room
temperature, but raised temperature increases the risk.
Yes
Pine Tar 60 – 65 %, Linseed oil, boiled 15 – 20 %, Fe2O3 5 – 10 %, Fe3O4 5 – 10 %,
FeO(OH) 5 – 10 %, 2-Ethylhexanoic acid, zirconium salt < 0,1 %, Fatty acids,
C6-19-branched, cobalt(2+)salts < 0,1 %
Warning
H317 May cause an allergic skin reaction. H412 Harmful to aquatic life with long lasting
effects.
P102 Keep out of reach of children. P273 Avoid release to the environment. P280
Wear protective gloves/protective clothing. P302+P352 IF ON SKIN: Wash with plenty
of soap and water. P333+P313 If skin irritation or rash occurs: Get medical advice /
attention. P501 Dispose of contents at hazardous or special waste collection point.
Product subcategory : Woodstain, oil or varnish for interior and exterior use.
Relevant VOC limit values: 700 g/l
Maximum content of VOC: <300 g/l
May cause sensitisation by skin contact.
None
Classification according to
67/548/EEC or 1999/45/EC
Classification according to
Regulation (EC) No 1272/
2008 [CLP / GHS]
Substance / mixture hazardous
properties
EC label
Composition on the label
Signal word
Hazard statements
Precautionary statements
VOC
Description of hazard
Other hazards
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Linseed oil, boiled CAS No.: 8001-26-1
EC No.: 232-278-6
15 – 20 %
Fe2O3 CAS No.: 1309-37-1
EC No.: 215-168-2
5 – 10 %
Fe3O4 CAS No.: 1317-61-9
EC No.: 215-277-5
5 – 10 %
FeO(OH) CAS No.: 20344-49-4
EC No.: 243-746-4
5 – 10 %
2-Ethylhexanoic acid, zirconium
salt
CAS No.: 22464-99-9
EC No.: 245-018-1
Rep 3; R63
Repr. 2; H361fd
< 0,1 %
Fatty acids, C6-19-branched,
cobalt(2+) salts
CAS No.: 68409-81-4
EC No.: 270-066-5
Xn; R22
Xi; R38,R43
N; R51/53
Acute tox. 4; H302
Skin Irrit. 2; H315
Skin Irrit. 2; H319
Skin Sens. 1; H317
Aquatic Chronic 2; H411
Asp. tox 1; H304
< 0,1 %
SECTION 4: First aid measures
4.1. Description of first aid measures
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: Firefighting measures
5.1. Extinguishing media
See section 16 for explanation of Risk-phrases (R) and hazard statements
(H) listed above.
Contains tall oil pitch, rosin acids, neutral matters such as fatty alcohols and phytosterin
and a small amount of terpenes (CAS-nr 8006-64-2, EG-nr 232-350-7)
Fresh air.
Wash the skin with water and soap. Remove contaminated clothing.
Flush immediately with water for at least 5 minutes. Get medical attention if any
discomfort continues.
Give water to drink if the affected person is fully conscious. Never give anything by
mouth to an unconscious person. DO NOT INDUCE VOMITING! Immediately consult a
doctor.
Gently wash with plenty of soap and water.
No information available.
Dry chemical, foam or carbon dioxide (CO2).
Remarks, substance
Substance comments
Inhalation
Skin contact
Eye contact
Ingestion
Information for health personnel
Specific details on antidotes
Suitable extinguishing media
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5.2. Special hazards arising from the substance or mixture
5.3. Advice for firefighters
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.2. Environmental precautions
6.3. Methods and material for containment and cleaning up
6.4. Reference to other sections
SECTION 7: Handling and storage
7.1. Precautions for safe handling
7.2. Conditions for safe storage, including any incompatibilities
7.3. Specific end use(s)
SECTION 8: Exposure controls / personal protection
8.1. Control parameters
Substance Identification Value TWA Year
Fatty acids, C6-19-branched,
cobalt(2+) salts
CAS No.: 68409-81-4
EC No.: 270-066-5
TWA (8h) : 100 mg/m³
TWA (8h) : 15 ppm
OEL short term value
Value: 200 mg/m³
Combustible. Not flammable.
Rags, steel wool, or waste soaked with linseed oil may
spontaneously catch fire if improperly discarded.
General: Evacuate all personnel, use protective equipment for fire fighting. Use a
portable breathing apparatus when the product is involved in a fire.
Use appropriate protective equipment.
Do not allow spill to enter sewers or watercourses.
Collect with absorbent, non-combustible material into suitable containers. Destroy
according to applicable regulations.
See Section 8 and section 13.
Wear prescribed personal protective equipment.
Keep only in original container. No specific storage precautions.
See Section 1.2
Fire and explosion hazards
Hazardous combustion
products
Personal protective equipment
Personal protection measures
Environmental precautionary
measures
Cleaning method
Other instructions
Handling
Storage
Specific use(s)
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OEL short term value
Value: 30 ppm
DNEL / PNEC
8.2. Exposure controls
Safety signs
Respiratory protection
Hand protection
Eye / face protection
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
No information available.
No information available.
Provide good ventilation.
No respirator is normally needed. If ventilation is insufficient, suitable respiratory
protection must be applied. Respirator with A filter (brown).
Protective gloves must be used if there is a risk of direct contact or splashes. Use
protective gloves made of: PVA (the glove must not come in contact with water), nitrile
rubber. or viton rubber.
Wear approved, tight fitting safety glasses where splashing is probable.
Viscous liquid.
Brownish.
Characteristic.
Comments: Not determined.
Status: In delivery state
Value: ~ 4
Comments: Not determined.
Value: = 150 – 400 °C
Value: > 80 °C
Value: ~ 1200 kg/m³
Temperature: 20 °C
Summary of risk management
measures, human
Summary of risk management
measures, environment
Limitation of exposure on
workplace
Respiratory protection
Hand protection
Eye protection
Physical state
Colour
Odour
Odour limit
pH
Melting point / melting range
Boiling point / boiling range
Flash point
Specific gravity
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9.2. Other information
Other physical and chemical properties
SECTION 10: Stability and reactivity
10.1. Reactivity
10.2. Chemical stability
10.3. Possibility of hazardous reactions
10.4. Conditions to avoid
10.5. Incompatible materials
10.6. Hazardous decomposition products
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Acute toxicity, Mixture estimate
Potential acute effects
Soluble in organic solvents. Aromatic hydrocarbons. Ethanol
Insoluble in water
No further relevant information available.
The chemical is stable at the given use and storing conditions.
Stable with normal handling. Spontaneous combustion hazard when in contact with
textiles etc. Used textiles must be soaked in water.
No hazardous reactions known.
No information available.
Avoid contact with oxidizing agents.
No formation of hazardous decomposition products are expected under normal
conditions.
No aspiration hazards known.
May cause sensitisation by skin contact.
May cause: Stinging.
May cause: Indisposition. Stomach pain.
Solubility description
Solubility in water
Comments
Reactivity
Stability
Possibility of hazardous reactions
Conditions to avoid
Materials to avoid
Hazardous decomposition
products
Acute toxicity, human experience
Skin contact
Eye contact
Ingestion
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Delayed effects / repeated exposure
Carcinogenic, Mutagenic or Reprotoxic
SECTION 12: Ecological information
12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
SECTION 13: Disposal considerations
May cause an allergic skin reaction.
Based on available data, the classification criteria are not met.
Reliable information on eye effects is lacking. There is no reason to suspect such
effects, but handle it with care and report any symptoms or injuries to the manufacturer
or the distributor
May cause sensitisation by skin contact.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Does not present any cancer or reproductive hazards.
Based on available data, the classification criteria are not met.
The chemical structure does not suggest such an effect.
May cause longterm adverse effects in the aquatic environment.
Not readily degradable.
Has the potential to bioaccumulate.
Comments: Insoluble in water
The product does not contain any PBT or vPvB substance.
May cause long lasting harmful effects to aquatic life.
Skin corrosion / irritation, human
experience
Aspiration hazard, human
experience
Eye damage or irritation, human
experience
Sensitisation
STOT-single exposure
STOT-repeated exposure
Carcinogenicity, other information
Assessment of germ cell
mutagenicity, classification
Reproductive toxicity
Ecotoxicity
Persistence and degradability,
comments
Bioaccumulative potential
Water solubility
PBT assessment results
Other adverse effects, comments
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13.1. Waste treatment methods
SECTION 14: Transport information
14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
14.4. Packing group
14.5. Environmental hazards
14.6. Special precautions for user
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations / legislation specific for the substance
or mixture
15.2. Chemical safety assessment
SECTION 16: Other information
Dispose of in compliance with local regulations.
Yes
No
EWC: 03 02 99 wood preservatives not otherwise specified
Not classified as hazardous for transport.
2006/121/2006
The product is classified and labelled in accordance with EEC guidelines or national
legislation.
Regulation (EC) nr. 1907/2006 Regulation (EC) nr. 1272/2008.
No
R43 May cause sensitization by skin contact. R52/53 Harmful to aquatic organisms,
may cause long-term adverse effects in the aquatic environment.
S-2 Keep out of the reach of children. S-24 Avoid contact with skin. S-28 After contact
with skin, wash immediately with plenty of water. S-37 Wear suitable gloves. S-46 If
swallowed, seek medical advice immediately and show this container or label. S61
Avoid release to the environment. Refer to special instructions/safety data sheets.
Specify the appropriate
methods of disposal
Product classified as hazardous
waste
Packaging classified as hazardous
waste
EWC waste code
Comments
EEC-directive
References (laws/regulations)
Legislation and regulations
Chemical safety assessment
performed
R-phrases
S-phrases
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These data are based on our best knowledge to date, however they do not imply any
guarantee on the properties or quality of the product. In case of uncertainties we advise
you to make own tests or ask for written directions from us.
R43 May cause sensitization by skin contact.
R38 Irritating to skin.
R63 Possible risk of harm to the unborn child.
R22 Harmful if swallowed.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
H302 Harmful if swallowed.
H412 Harmful to aquatic life with long lasting effects.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
H411 Toxic to aquatic life with long lasting effects.
H319 Causes serious eye irritation.
Skin Sens. 1; H317;
Aquatic Chronic 3; H412;
6
21.09.2019
Supplier’s notes
List of relevant R-phrases
(under headings 2 and 3).
List of relevant H-phrases
(Section 2 and 3)
Classification according to
Regulation (EC) No 1272/
2008 [CLP / GHS]
Version
Expired date
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