Pine Tar Vitriol Safety Data Sheet

The safety data sheet is in accordance with Commission Regulation (EU) 2015/830 of 28 May 2015 amending Regulation
(EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation
and Restriction of Chemicals (REACH)
SECTION 1: Identification of the substance / mixture and of the company /
undertaking
1.1. Product identifier
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
Manufacturer
1.4. Emergency telephone number
SAFETY DATA SHEET
Pine Tar Vitriol
14.09.2016
Pine Tar Vitriol
Tar solution
60590
Wood protection
SU21 Consumer uses: Private households (= general public = consumers)SU22
Professional uses: publicly accessible (administration, education, entertainment,
services, craftsmen)PC9 Coatings and Paints, Fillers, Putties, ThinnersPC15 Products
for treatment of non-metal surfaces
Auson AB
Verkstadsgatan 3
S-434 42
KUNGSBACKA
SVERIGE
+46 300-562000
+46 300-562021
nina.nyth@auson.se
https://www.auson.se/
Nina Nyth
Telephone number: 112
Date issued
Product name
Chemical name
Article no.
Use of the substance /
preparation
Relevant identified uses
Company name
Postal address
Postcode
City
Country
Telephone number
Fax
Email
Website
Contact person
Emergency telephone
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SECTION 2: Hazards identification
2.1. Classification of substance or mixture
2.2. Label elements
Hazard pictograms (CLP)
Description: SOS Alarm
Xn,N; R10,R20/21/22,R36/38,R43,R51/53,R65
Flam. Liq. 3; H226
Acute tox. 4; H302
Acute tox. 4; H312
Acute tox. 4; H332
Skin Irrit. 2; H315
Eye Irrit. 2; H319
Skin Sens. 1; H317
Asp. tox 1; H304
Aquatic Chronic 2; H411
Yes
Turpentine, vegetable. 50 – 55 %, Pine Tar 40 – 45 %, Naphtha (petroleum),
hydrotreated heavy, benzene < 0,1% 2 – 3 %
Danger
H226 Flammable liquid and vapour. H302 Harmful if swallowed. H312 Harmful in
contact with skin. H332 Harmful if inhaled. H315 Causes skin irritation. H319 Causes
serious eye irritation. H317 May cause an allergic skin reaction. H304 May be fatal if
swallowed and enters airways. H411 Toxic to aquatic life with long lasting effects.
P102 Keep out of reach of children. P210 Keep away from heat, hot surfaces, sparks,
open flames and other ignition sources. No smoking. P233 Keep container tightly
closed. P261 Avoid breathing dust/fume/mist. P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing. P301+P310 IF SWALLOWED:
Immediately call a POISON CENTER or doctor / physician. P302+P352 IF ON SKIN:
Wash with plenty of soap and water. P405 Store locked up. P501 Dispose of contents
at hazardous or special waste collection point.
Product subcategory : Woodstain, oil or varnish for interior and exterior use.
Relevant VOC limit values: 700 g/l
Maximum content of VOC: 487 g/l
Classification according to
67/548/EEC or 1999/45/EC
Classification according to
Regulation (EC) No 1272/
2008 [CLP / GHS]
EC label
Composition on the label
Signal word
Hazard statements
Precautionary statements
VOC
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2.3. Other hazards
SECTION 3: Composition / information on ingredients
3.2. Mixtures
Substance Identification Classification Contents
Turpentine, vegetable. CAS No.: 8006-64-2
EC No.: 232-350-7
Xn,N; R10,R20/21/22,R36/
38,R43,R51/53,R65
Aquatic Chronic 2;H411
Asp. tox 1;H304
Skin Sens. 1;H317
Eye Irrit. 2;H319
Skin Irrit. 2;H315
Acute tox. 4;H332
Acute tox. 4;H312
Acute tox. 4;H302
Flam. Liq. 3;H226
50 – 55 %
Pine Tar CAS No.: 8011-48-1
EC No.: 232-374-8
Xi; R43
R52/53
Skin Sens. 1;H317
Aquatic Chronic 3; H412
40 – 45 %
Naphtha (petroleum) , hydrotreated
heavy, benzene <
0,1%
CAS No.: 64742-48-9
EC No.: 265-150-3
Index No.: 649-327-00-6
Xn; R10,R65,R66,R67
Flam. Liq. 3; H226
Asp. tox 1; H304
STOT SE3; H336
EUH 066
2 – 3 %
SECTION 4: First aid measures
4.1. Description of first aid measures
4.2. Most important symptoms and effects, both acute and delayed
Flammable Harmful by inhalation, in contact with skin and if swallowed. Irritating to
eyes and skin. May cause sensitisation by skin contact. Toxic to aquatic organisms,
may cause long-term adverse effects in the aquatic environment. Harmful: may cause
lung damage if swallowed.
None
See section 16 for explanation of Risk-phrases (R) and hazard statements
(H) listed above.
Fresh air and rest. Get medical advice if large amounts have been inhaled or the
patient experiences discomfort.
Remove contaminated clothing. Wash skin thoroughly with soap and water. Get
medical advice if irritation persists.
Flush immediately with water for at least 5 minutes. Keep eye wide open while flushing.
Get medical attention if any discomfort continues.
Immediately give a few tablespoons of cooking oil, sour cream, cream, or melted ice
cream (NB! large amounts of fat) if the patient is fully conscious. DO NOT INDUCE
VOMITING! In an emergency, contact the national Poisons Information Centre.
Description of hazard
Other hazards
Remarks, substance
Inhalation
Skin contact
Eye contact
Ingestion
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4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: Firefighting measures
5.1. Extinguishing media
5.2. Special hazards arising from the substance or mixture
5.3. Advice for firefighters
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
6.2. Environmental precautions
6.3. Methods and material for containment and cleaning up
6.4. Reference to other sections
SECTION 7: Handling and storage
7.1. Precautions for safe handling
7.2. Conditions for safe storage, including any incompatibilities
No further relevant information available.
No information available.
Dry chemical, foam or carbon dioxide (CO2).
Do not use a direct water jet that could spread the fire.
Heating leads to formation of combustible vapour which may form explosive mixture
with air. Spontaneous combustion hazard.
Containers close to fire should be removed immediately or cooled with water.
Use the specified protective equipment. Evacuate the area.
Do not allow spill to enter sewers or watercourses. Inform appropriate authorities if
large amounts are involved.
Avoid release to the environment. Cover drains.
Absorb in a special absorbent and transport to approved waste management facility.
Always use earth (ground) wire when transferring from one container to another. Avoid
contact with skin and eyes. Avoid inhalation of vapours.
Keep away from sources of ignition – No smoking. Store in original container. Keep in a
General symptoms and effects
Specific details on antidotes
Suitable extinguishing media
Improper extinguishing media
Fire and explosion hazards
Other information
Personal protection measures
Environmental precautionary
measures
Cleaning method
Other instructions
Handling
Storage
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7.3. Specific end use(s)
SECTION 8: Exposure controls / personal protection
8.1. Control parameters
Substance Identification Value TWA Year
Turpentine, vegetable. CAS No.: 8006-64-2
EC No.: 232-350-7
TWA (8h) : 25 ppm
TWA (8h) : 150 mg/m³
OEL short term value
Value: 50 ppm
OEL short term value
Value: 300 mg/m³
TWA Year: 1990
Naphtha (petroleum) , hydrotreated
heavy, benzene <
0,1%
CAS No.: 64742-48-9
EC No.: 265-150-3
Index No.: 649-327-00-6
TWA (8h) : 50 ppm
TWA (8h) : 300 mg/m³
OEL short term value
Value: 100 ppm
OEL short term value
Value: 600 mg/m³
TWA Year: 2011
DNEL / PNEC
8.2. Exposure controls
Safety signs
Respiratory protection
Hand protection
well-ventilated place. Keep container tightly closed.
Avoid contact with strong oxidizing agents.
See Section 1.2
No information available.
No information available.
Provide good ventilation. Keep containers closed, as much as possible. No smoking,
fire, sparks or welding. Eyewash facilities should be available at the workplace.
Wear suitable respiratory equipment if ventilation is insufficient. Respirator with A filter
(brown).
Protective gloves must be used if there is a risk of direct contact or splashes. Use
suitable protective gloves made of nitrile rubber.
Special risks and properties
Specific use(s)
Summary of risk management
measures, human
Summary of risk management
measures, environment
Limitation of exposure on
workplace
Respiratory protection
Hand protection
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Eye / face protection
Skin protection
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
9.2. Other information
Other physical and chemical properties
SECTION 10: Stability and reactivity
10.1. Reactivity
10.2. Chemical stability
10.3. Possibility of hazardous reactions
10.4. Conditions to avoid
Wear approved, tight fitting safety glasses where splashing is probable.
Protective clothing must be worn if there is a possibility of direct contact or splashes.
Free-flowing liquid.
Greyish brown.
Tar.
Comments: Not determined.
Comments: Not determined.
Value: > 140 °C
Value: = 35 °C
Comments: No data recorded.
Value: = 940 kg/m³
Temperature: 20 °C
Soluble in organic solvents.
Slight soluble in water
No further relevant information available.
Keep away from heat / sparks / open flames / hot surfaces. — No smoking.
Stable with normal handling.
No hazardous reactions known.
No information available.
Eye protection
Skin protection (except
hands)
Physical state
Colour
Odour
Odour limit
Melting point / melting range
Boiling point / boiling range
Flash point
Vapour pressure
Specific gravity
Solubility description
Solubility in water
Comments
Reactivity
Stability
Possibility of hazardous reactions
Conditions to avoid
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10.5. Incompatible materials
10.6. Hazardous decomposition products
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Toxicological data for substances
Acute toxicity, Mixture estimate
Strong oxidizing agents.
No formation of hazardous decomposition products are expected under normal
conditions.
Turpentine, vegetable.
Type of toxicity: Acute
Effect tested: LC50
Route of exposure: Inhalation.
Duration: 6 h
Value: 12000 mg/m³
Animal test species: rat
Type of toxicity: Acute
Effect tested: LD50
Route of exposure: Oral
Value: 5760 mg/kg
Animal test species: rat
Naphtha (petroleum), hydrotreated heavy, benzene < 0,1%
Type of toxicity: Acute
Effect tested: LD50
Route of exposure: Oral
Value: > 2000 mg/kg
Animal test species: rat
Type of toxicity: Acute
Effect tested: LD50
Route of exposure: Dermal
Value: > 2000 mg/kg
Animal test species: rabbit
Type of toxicity: Acute
Effect tested: LC50
Route of exposure: Inhalation.
Duration: 4h
Value: > 5000 mg/m³
Animal test species: rat
No aspiration hazards known.
Materials to avoid
Hazardous decomposition
products
Substance
Acute toxicity
Substance
Acute toxicity
Acute toxicity, human experience
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Potential acute effects
Delayed effects / repeated exposure
Carcinogenic, Mutagenic or Reprotoxic
SECTION 12: Ecological information
12.1. Toxicity
Toxicological data for substances
May cause slight irritation to the mucous membranes in the nose and upper respiratory
tract. May cause Headache. Dizziness. Fatigue.
Defats the skin. Irritating to skin.
May cause irritation/smarting.
Smarting in mouth and throat. Abdominal pains. Vomiting. Causes similar symptoms as
by inhalation. Chemical pneumonitis may develop in from a few hours to up to a day
after ingestion of the product, or if vomit has entered the lungs.
May cause an allergic skin reaction.
Aspiration may cause chemical pneumonitis.
Causes serious eye irritation.
Based on available data, the classification criteria are not met.
Based on available data, the classification criteria are not met.
Does not present any cancer or reproductive hazards.
The chemical structure does not suggest a mutagenic effect.
The chemical structure does not suggest such an effect.
May cause longterm adverse effects in the aquatic environment.
Naphtha (petroleum), hydrotreated heavy, benzene < 0,1%
Value: > 100 mg/L
Test duration: 96h
Method: LC50
Value: > 100 mg/L
Test duration: 72h
Method: EC50
Value: > 100 mg/L
Test duration: 48h
Method: EC50
Low toxicity for aquatic organisms. Available data indicates that only larger local
discharges may cause a risk.
Inhalation
Skin contact
Eye contact
Ingestion
Skin corrosion / irritation, human
experience
Aspiration hazard, comments
Eye damage or irritation, human
experience
STOT-single exposure
STOT-repeated exposure
Carcinogenicity, other information
Assessment of germ cell
mutagenicity, classification
Reproductive toxicity
Ecotoxicity
Substance
Acute aquatic, fish
Acute aquatic, algae
Acute aquatic, Daphnia
Aquatic, comments
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12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
SECTION 13: Disposal considerations
13.1. Waste treatment methods
SECTION 14: Transport information
14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
Not readily degradable.
No information available
Comments: Insoluble in water
The product does not contain any PBT or vPvB substance.
Toxic to aquatic organisms, may cause long-term adverse effect in the aquatic
environment.
Dispose of in compliance with local regulations. Residues must be treated as
hazardous waste.
Yes
No
EWC: 03 02 05 other wood preservatives containing dangerous substances
1299
1299
1299
Pine Tar Vitriol
TURPENTINE
TURPENTINE
TURPENTINE
Persistence and degradability,
comments
Bioaccumulative potential
Water solubility
PBT assessment results
Other adverse effects, comments
Specify the appropriate
methods of disposal
Product classified as hazardous
waste
Packaging classified as hazardous
waste
EWC waste code
ADR / RID / ADN
IMDG
ICAO / IATA
Proper shipping name english
ADR / RID / ADN
ADR / RID / ADN
IMDG
ICAO / IATA
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14.4. Packing group
14.5. Environmental hazards
14.6. Special precautions for user
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Additional information
ADR / RID – Other information
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations / legislation specific for the substance
or mixture
15.2. Chemical safety assessment
SECTION 16: Other information
3
3
3
III
III
III
Yes
Yes
Yes
F-E, S-E
Limited quantity
30
2006/121/2006
The product is classified and labelled in accordance with EEC guidelines or national
legislation.
Regulation (EC) nr. 1907/2006 Regulation (EC) nr. 1272/2008.
No
R10 Flammable. R20/21/22 Harmful by inhalation, in contact with skin and if
swallowed. R36/38 Irritating to eyes and skin. R43 May cause sensitization by skin
contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in
ADR / RID / ADN
IMDG
ICAO / IATA
ADR / RID / ADN
IMDG
ICAO / IATA
ADR / RID / ADN
IMDG
IMDG Marine pollutant
EmS
Additional information
Hazard No.
EEC-directive
References (laws/regulations)
Legislation and regulations
Chemical safety assessment
performed
R-phrases
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the aquatic environment. R65 Harmful: may cause lung damage if swallowed.
S-2 Keep out of the reach of children. S-51 Use only in well-ventilated areas. S-56
Dispose of this material and its container at hazardous or special waste collection point.
S-62 If swallowed, do not induce vomiting: seek medical advice immediately and show
this container or label.
These data are based on our best knowledge to date, however they do not imply any
guarantee on the properties or quality of the product. In case of uncertainties we advise
you to make own tests or ask for written directions from us.
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic
environment.
R65 Harmful: may cause lung damage if swallowed.
R36/38 Irritating to eyes and skin.
R67 Vapours may cause drowsiness and dizziness.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R10 Flammable.
R66 Repeated exposure may cause skin dryness or cracking.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
H302 Harmful if swallowed.
H412 Harmful to aquatic life with long lasting effects.
H304 May be fatal if swallowed and enters airways.
H226 Flammable liquid and vapour.
H336 May cause drowsiness or dizziness.
H315 Causes skin irritation.
H332 Harmful if inhaled.
H317 May cause an allergic skin reaction.
EUH 066 Repeated exposure may cause skin dryness or cracking.
H312 Harmful in contact with skin.
H411 Toxic to aquatic life with long lasting effects.
H319 Causes serious eye irritation.
Flam. Liq. 3; H226;
Acute tox. 4; H302;
Asp. tox 1; H304;
Acute tox. 4; H312;
Skin Irrit. 2; H315;
Skin Sens. 1; H317;
Eye Irrit. 2; H319;
Acute tox. 4; H332;
Aquatic Chronic 2; H411;
4
14.09.2019
S-phrases
Supplier’s notes
List of relevant R-phrases
(under headings 2 and 3).
List of relevant H-phrases
(Section 2 and 3)
Classification according to
Regulation (EC) No 1272/
2008 [CLP / GHS]
Version
Expired date
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