SAFETY DATA SHEET Gum Turpentine

SAFETY DATA SHEET
Gum Turpentine

SDS according to Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation and
Restriction of Chemicals (REACH), Annex II-EU

SECTION 1: Identification of the substance/mixture and of the
company/undertaking

Date issued 17.06.2014

1.1. Product identifier

Product name Gum Turpentine
Chemical name Turpentine
CAS no. 8006-64-2
EC no. 232-350-7
Article no. 66606

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/preparation Solvent
Relevant identified uses SU8 Manufacture of bulk, large scale chemicals (including petroleum products)

1.3. Details of the supplier of the safety data sheet

Distributor
Company name Auson AB
Postal address Verkstadsgatan 3
Postcode S-434 42
City KUNGSBACKA
Country SVERIGE
Tel +46 300-562000
Fax +46 300-562021
E-mail nina.nyth@auson.se
Website https://www.auson.se/
Contact person Nina Nyth

1.4. Emergency telephone number

Emergency telephone .:112

SECTION 2: Hazards identification

2.1. Classification of substance or mixture

Classification according to
67/548/EEC or 1999/45/EC
Xn,N; R10,R20/21/22,R36/38,R43,R51/53,R65
Classification according to
Regulation (EC) No 1272/2008
[CLP/GHS]
Flam. Liq. 3; H226
Acute tox. 4; H302, H312, H332
Skin Irrit. 2; H315
Eye Irrit. 2; H319
Skin Sens. 1; H317
Asp. tox 1; H304
Aquatic Chronic 2; H411

2.2. Label elements

EC label Yes
Hazard Pictograms (CLP)
Gum Turpentine Page 1 of 7
Composition on the label Turpentine, vegetable.:= 100 %
Signal word Danger
Hazard statements H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be
fatal if swallowed and enters airways. H312 Harmful in contact with skin.
H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319
Causes serious eye irritation. H332 Harmful if inhaled. H411 Toxic to aquatic
life with long lasting effects.
Precautionary statements P102 Keep out of reach of children. P210 Keep away from heat/sparks/open
flames/hot surfaces. ???? No smoking. P280 Wear protective gloves/protective
clothing/ eye protection. P303 + P361 + P353 IF ON SKIN (or hair):
Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER or doctor/physician. P331 Do NOT induce vomiting. P403 + P235
Store in a well-ventilated place. Keep cool. P501 Dispose of
contents/container at hazardous or special waste collection point.

2.3. Other hazards

Description of hazard Flammable Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes and skin. May cause sensitisation by skin contact. Toxic to
aquatic organisms, may cause long-term adverse effects in the aquatic
environment. Harmful: may cause lung damage if swallowed.

SECTION 3: Composition/information on ingredients

3.1. Substances

Substance Identification Classification Contents
Turpentine, vegetable. CAS no.: 8006-64-2
EC no.: 232-350-7
Xn,N; R10,R20/21/22,
R36/38,R43,R51/53,R65
Aquatic Chronic 2;H411
Asp. tox 1;H304
Skin Sens. 1;H317
Eye Irrit. 2;H319
Skin Irrit. 2;H315
Acute tox. 4;H332
Acute tox. 4;H312
Acute tox. 4;H302
Flam. Liq. 3;H226
= 100 %

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Fresh air and rest. Respiratory help if necessary. Consult a doctor if
symptoms should occur.
Skin contact Wash the skin with water and soap. Remove contaminated clothing.
Eye contact Flush immediately with water for at least 5 minutes. Get medical attention if
any discomfort continues.
Ingestion Give water to drink if the affected person is fully conscious. DO NOT
INDUCE VOMITING! Never give anything by mouth to an unconscious person.
In an emergency, contact the national Poisons Information Centre.

4.2. Most important symptoms and effects, both acute and delayed

Information for health personnel Risk of chemical pneumonia (pneumonitis) if aspirated during and after
ingestion.

4.3. Indication of any immediate medical attention and special treatment needed

Gum Turpentine Page 2 of 7
Specific details on antidotes No information available.

SECTION 5: Firefighting measures
5.1. Extinguishing media

Suitable extinguishing media Dry chemical, foam or carbon dioxide (CO2).

5.2. Special hazards arising from the substance or mixture

Fire and explosion hazards Flammable. Vapours may form explosive mixtures with air.

5.3. Advice for firefighters

Personal protective equipment General: Evacuate all personnel, use protective equipment for fire fighting.
Use a portable breathing apparatus when the product is involved in a fire.
Other Information Containers close to fire should be removed immediately or cooled with water.

SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

Personal protection measures Evacuate the area. Keep the general public away from danger area.

6.2. Environmental precautions

Environmental precautionary
measures
Do not allow spill to enter sewers or watercourses. Inform appropriate
authorities if large amounts are involved.

6.3. Methods and material for containment and cleaning up

Cleaning method Collect with absorbent, non-combustible material into suitable containers.
Destroy according to applicable regulations.

6.4. Reference to other sections
SECTION 7: Handling and storage
7.1. Precautions for safe handling

Handling Wear prescribed personal protective equipment. Avoid smoking, open flames,
welding etc. Provide adequate ventilation.

7.2. Conditions for safe storage, including any incompatibilities

Storage Keep away from sources of ignition – No smoking. Keep container tightly
closed. Store in original container.
Special risks and properties Avoid contact with strong oxidizing agents.

7.3. Specific end use(s)
SECTION 8: Exposure controls/personal protection
8.1. Control parameters

Occupational Exposure limit values
Substance Identification Value TWA Year
Turpentine, vegetable. CAS no.: 8006-64-2
EC no.: 232-350-7
8-hour TWA: 25 ppm
8-hour TWA: 150 mg/m³
15 min.: 50 ppm
15 min.: 300 mg/m³
1990
DNEL / PNEC
Summary of risk management
measures, human
No information available.
Summary of risk management
measures, environment
No information available.

8.2. Exposure controls

Limitation of exposure on workplace Provide good ventilation. No smoking, fire, sparks or welding. Eyewash
facilities should be available at the workplace.
Gum Turpentine Page 3 of 7
Safety signs
Respiratory protection
Respiratory protection Respirator with A filter (brown).
Hand protection
Hand protection Protective gloves must be used if there is a risk of direct contact or
splashes. Use protective gloves made of: viton rubber.
Eye / face protection
Eye protection Wear approved, tight fitting safety glasses where splashing is probable.
Skin protection
Skin protection (except hands) Wear suitable protective clothing.

SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties

Physical state Volatile liquid.
Colour Colourless.
Odour Strong. Characteristic.
Boiling point / boiling range Value: = 150-180 °C
Flash point Value: = 35 °C
Explosion limit Value: 0,8-6 %
Vapour pressure Value: = 0,67 kPa
Vapour density Value: ~ 1
Specific gravity Value: = 855-870 kg/m³
Solubility description Soluble in organic solvents.
Solubility in water Slightly soluble in water
Spontaneous combustability Value: = 220 °C

9.2. Other information
SECTION 10: Stability and reactivity
10.1. Reactivity
10.2. Chemical stability
Stability Stable with normal handling.
10.3. Possibility of hazardous reactions
10.4. Conditions to avoid
10.5. Incompatible materials

Materials to avoid Reacts violently with oxidizers.

10.6. Hazardous decomposition products

Hazardous decomposition products Carbon dioxide (CO2). Carbon monoxide (CO).

SECTION 11: Toxicological information
11.1. Information on toxicological effects

Toxicological data for substances
Substance Turpentine, vegetable.
LD50 oral Value: 5760 mg/kg
Animal test species: rat
LC50 inhalation Value: 12000 mg/m³
Gum Turpentine Page 4 of 7
Animal test species: rat
Duration: 6 h
Potential acute effects
Inhalation Coughing. Dizziness. Headache. Fatigue. Indisposition. May cause a burning
sensation in nose and throat. Influence on hart. Kidney damage.
Unconsciousness.
Skin contact Defats the skin. Dermal fissure. Blush. Prolonged or repeated skin contact
may cause dermatitis. Product may penetrate skin by prolonged exsposure
and give similar symptoms as by inhalation.
Eye contact Irritation.
Ingestion May cause a burning sensation in nose and throat. Abdominal pains.
Vomiting. Diarrhoea. Causes similar symptoms as by inhalation. May cause:
Pneumonia.

SECTION 12: Ecological information
12.1. Toxicity
Ecotoxicity Toxic to aquatic organisms.
Toxicological data for substances
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment

PBT assessment results No information available.

12.6. Other adverse effects

Other adverse effects / Remarks May cause long-term adverse effects in the aquatic environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Specify the appropriate methods of
disposal
Should be prevented from entering drain. Dispose of in compliance with local
regulations.
Product classified as hazardous
waste
Yes
Packaging classified as hazardous
waste
No
EWC waste code EWC: 14 06 03 other solvents and solvent mixtures

SECTION 14: Transport information
14.1. UN number
ADR 1299
RID 1299
IMDG 1299
ICAO/IATA 1299
14.2. UN proper shipping name

ADR TURPENTINE
RID TURPENTINE
IMDG TURPENTINE
ICAO/IATA TURPENTINE

14.3. Transport hazard class(es)

ADR 3
Hazard no. 30
Gum Turpentine Page 5 of 7
RID 3
IMDG 3
ICAO/IATA 3

14.4. Packing group

ADR III
RID III
IMDG III
ICAO/IATA III

14.5. Environmental hazards
14.6. Special precautions for user

EmS F-E, S-E

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Additional information.
Additional information. Limited quantity

SECTION 15: Regulatory information

EC no. 232-350-7

15.1. Safety, health and environmental regulations/legislation specific for thee

substance or mixture
EEC-directive 2006/121/2006
References (laws/regulations) The product is classified and labelled in accordance with EEC guidelines or
national legislation.
Legislation and regulations Regulation (EC) nr. 1907/2006 Regulation (EC) nr. 1272/2008.

15.2. Chemical safety assessment
SECTION 16: Other information

R-phrases R10 Flammable. R20/21/22 Harmful by inhalation, in contact with skin and if
swallowed. R36/38 Irritating to eyes and skin. R43 May cause sensitization by
skin contact. R51/53 Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment. R65 Harmful: may cause lung
damage if swallowed.
S-phrases S-2 Keep out of the reach of children. S29 Do not empty into drain. S36/37
Wear suitable protective clothing and gloves. S-56 Dispose of this material
and its container at hazardous or special waste collection point. S-62 If
swallowed, do not induce vomiting: seek medical advice immediately and
show this container or label.
Supplier’s notes These data are based on our best knowledge to date, however they do not
imply any guarantee on the properties or quality of the product. In case of
uncertainties we advise you to make own tests or ask for written directions
from us.
Expired date 17.06.2017
Classification according to
Regulation (EC) No 1272/2008
[CLP/GHS]
Flam. Liq. 3; H226;
Acute tox. 4; H302;
Asp. tox 1; H304;
Acute tox. 4; H312;
Skin Irrit. 2; H315;
Skin Sens. 1; H317;
Eye Irrit. 2; H319;
Acute tox. 4; H332;
Aquatic Chronic 2; H411;
List of relevant R-phrases (under
headings 2 and 3).
R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverseeffects in
the aquatic environment.
Gum Turpentine Page 6 of 7
R65 Harmful: may cause lung damage if swallowed.
R36/38 Irritating to eyes and skin.
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R10 Flammable.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
List of relevant H-phrases (Section
2 and 3).
H332 Harmful if inhaled.
H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H312 Harmful in contact with skin.
H304 May be fatal if swallowed and enters airways.
H226 Flammable liquid and vapour.
H411 Toxic to aquatic life with long lasting effects.
H319 Causes serious eye irritation.
H315 Causes skin irritation.
Version 9
Responsible for safety data sheet Auson AB
Gum Turpentine Page 7 of 7